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| John Steed | Patrick Macnee {007} |
| Catherine Gale | Honor Blackman {007} {Dr Who} |
| Julius Redfern | Peter Arne {regular} {Dangerman} {The Saint} {Pink Panther} {Department S} {The Champions} |
| Elizabeth Bayle | Pauline Delany (Delaney) {regular} |
| Dr. Ashe | Donald Eccles {Adam Adamant} {Dr Who} |
| Leo DeLeon | Gordon Whiting {regular} {Dangerman} {The Saint} |
| Hillier | Robert Bernal {Dangerman} |
| Diana DeLeon | Irene Bradshaw {regular} |
| Campbell | Louis Haslar |
| Hall | Charles (Charlie) Bird {regular} |
| Teleplay by | Martin Woodhouse |
| Story Editor | Richard Bates |
| "The Avengers" theme composed and played by | Johnny Dankworth |
| Designed by | Douglas James {007} |
| Producer | John Bryce |
| Directed by | Peter Hammond |
| Production Assistant | Jill Horwood |
| Floor Manager | Denver Thornton {The New Professionals} |
| Stage Manager | Betty Crowe |
| Technical Supervisor | Peter Wayne |
| Lighting Supervisor | Ken Brown |
| Senior Cameraman | Dickie Jackman |
| Sound Supervisor | John Tasker |
| Vision Mixer | Del Randall |
| Wardrobe Supervisor | Ambren Garland |
| Make-up Supervisor | Lee Halls |
| An ABC Production | |